Technically yes you should be able to. iChat uses the AIM protocol, and it "should" work if your friend use iChat (obviously), AOL AIM or Trillian. How she goes about in her program to see your webcam I cannot tell you unfortunately, but I remember that AIM compatibility was a big thing when it was originally launched in Panther.
Don't Panic! See my Mac-Help blog for procedures, tips, tricks and things you can do before and during a problem.
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