Finder has menus at the top of the screen one of those is the Go menu.
If you hold down the Option Key while using the Go Menu you will see Library between Home and Computer choose it there takes you straight to your Library.
If you really need to go there often, you can Click/Hold the Little Library Folder Icon in the Library Window Titlebar, then drag it to either the Toolbar or Sidebar Favourites. Then its only a click away.
You should also be aware that if Migration Assistant failed to migrate your Preferences it may have had its reasons, there is nothing worse for making a crashie Mac than corrupt, damaged or wrong Preference Files. So if you have manually added the plist files proceed with caution.
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